Given an array of positive integers, write a function which returns all the unique pairs which add (equal) up to 100.
Example data:
sample_data = [0, 1, 100, 99, 0, 10, 90, 30, 55, 33, 55, 75, 50, 51, 49, 50, 51, 49, 51]
sample_output = [[1,99], [0,100], [10,90], [51,49], [50,50]]